High-Value Mixed Rare Earth Carbonate Produced For Ema
Released
Released
Announcement PDF
ASX Announcement
Released 11th November 2024
HIGH-VALUE MIXED RARE EARTH CARBONATE PRODUCT
SUCCESSFULLY PRODUCED FOR EMA PROJECT
EMA POSITIONED TO BECOME AN INDUSTRY LEADING IONIC CLAY REE PRODUCER
Highlights
•
ANSTO test work demonstrates the ability to produce a high value bulk mixed rare earth
carbonate (MREC) product from Ema ionic clay rare earth material
•
Magnet rare earth elements (MREE’s) comprised a very high 38% of final REO basket
composition
•
High TREO content in final MREC calculated at 55.3%, now setting an industry benchmark for a
basket price to be developed utilising magnesium sulfate (Figure 3)
•
MREC production utilised an environmentally friendly magnesium-based reagent stream,
eliminating use of ammonium
•
High purity (98%) low impurity (~2.0%) MREC, after only 30 minutes at target pH using
magnesium oxide
•
High MREE recoveries >99% in the MREC precipitation stage after 2 hours of mixing with at
target pH using magnesium bicarbonate
•
High TREO inside the final MREC delivers superior value basket prices for an ionic clay project
(Figure 3)
•
Results to be used to calculate CAPEX and OPEX pricing in the Scoping Study due for completion
by year’s end.
Andrew Reid, Managing Director, commented:
“BCM has a vision to create one of the most environmentally friendly and lowest cost rare earth mines globally. The
results from ANSTO confirm that BCM remains on track to achieve this goal by producing a high value final product
utilising environmentally responsible magnesium-based reagents. This is a significant milestone for the Company.
The Company is now increasingly confident in its ability to build a low-cost in-situ recovery rare earth project, having
exceeded all expectations over the last 6 months since the Mineral Resource Estimate was released.
In-situ recovery of rare earths, which currently produces some 30% of the world’s production, significantly simplifies
and removes at least 60% of the typical process flowsheet and much of the complexity when compared to traditional
methods of rare earth clay extraction. Not only is the complexity and capital cost hurdle far lower for development
of an ISR project, but the operating cost are also typically in the lowest quartile, which bodes well for our Ema
Project.
For the balance of this calendar year we will complete a large infill drilling campaign, finalise the scoping study,
complete some additional metallurgical testwork and continue with the environmental baseline assessment of the
project.”
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
Brazilian Critical Minerals Limited (ASX: BCM) (“BCM” or the “Company”) is pleased to announce the
results from metallurgical testwork on a bulk sample from the Ema Rare Earth Project in the Apuí region
of Brazil (Figure 1).
Figure 1. Location of the Ema Project, Brazil.
Test Work Program
The test program conducted by Australia’s Nuclear Science Organisation (ANSTO) focused on achieving
a viable, low-cost flowsheet utilising magnesium sulfate, magnesium oxide and magnesium bicarbonate
as the foundation chemicals through only 3 surface processing steps (Figure 2).
The objective was to develop a flowsheet using environmentally friendly reagents which would allow for
the development of low cost in-situ recovery of rare earths, avoiding all the potential harm and
degradation that comes with using ammonium-based reagents.
The goal was to ensure that the developed flowsheet could deliver high recovery rates, low impurities,
and a product quality that could be economically feasible, even in times of low prices of rare earth
elements (REEs).
Producing a high-value mixed rare earth carbonate confirms that the project has successfully refined
and concentrated several REEs into a form that can be further processed into pure, individual rare earth
oxides and metals. This is a significant milestone in the supply chain for industries that rely on these
materials, such as the green tech sector.
The successful outcome of this program underscores the potential for scalable and economically viable
operations at Ema with a focus on low cost and efficiency.
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
Final Product (MREC)
The Mixed Rare Earth Carbonate (MREC) produced from the test work contained 55.3% rare earth oxides
(REO) and only ~2.0% impurities based on test work conducted using a 41kg sample from the Ema 2
master composite sample. Through the impurity removal and carbonate precipitation process steps,
approximately 33.2 grams of high-quality MREC was generated, Figure 2.
Figure 2. Simple 4 step process flow sheet for ionic clay MREC production at Ema Project
This result highlights the efficiency of the magnesium sulfate process on the Ema material in producing
a high-grade, low-impurity MREC product, which is critical for meeting industry standards and optimizing
the economic viability of the project at the same time as generating outstanding revenue potential
through the basket price calculation (Figure 3). The purity level of the MREC positions this product as
highly competitive in the market, further validating the potential path taken to process the Ema
material.
The composition of the magnet elements in the final MREC and recoveries achieved through the
processing steps in testwork result in an exceptionally high basket price despite the significantly lower
head grade of the tested samples relative to our peers, and when combined with a potentially low-cost
mining and processing flow sheet, has the potential to place the project in a good position to tap into
the rapidly growing demand from industries (Figure 3). The table below compares the final MREC
products of BCM, with our key Brazilian peers, Viridis Mining and Minerals Ltd (VMM), and Meteoric
Resources NL (MEI).
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
BCM
VMM1
MEI1
965
Magnesium Sulfate
30 Minutes
4.5
0.3
4,472
Ammonium Sulfate
30 Minutes
4.5
0.3
4,439
Ammonium Sulfate
30 Minutes
4.5
0.5
La2O3
CeO2
Pr6O11
Nd2O3
Sm2O3
Eu2O3
Gd2O3
Tb4O7
Dy2O3
Ho2O3
Er2O3
Tm2O3
Yb2O3
Lu2O3
Head Grade (ppm)
Agent
Time
pH
Molar
Price (01.11.24)
USD/kg
$
0.56
$
1.01
$
60.45
$
60.45
$
2.10
$
27.35
$
24.68
$
839.95
$
247.42
$
72.54
$
42.60
$
113.31
$
14.06
$
759.12
Y2O3
$
FINAL MREC
Oxide
5.90
Basket Price (TREO)
Basket Price (NdPrDyTb)
MREO %
TREO %
%
Basket $
%
Basket $
%
Basket $
34.7
8.9
7.1
29.1
4.6
0.5
2.9
0.3
1.4
0.2
0.7
0.1
0.6
0.1
$
$
$
$
$
$
$
$
$
$
$
$
$
$
0.19
0.09
4.31
17.61
0.10
0.15
0.71
2.28
3.39
0.18
0.30
0.11
0.08
0.64
44.5
2.4
8.3
29.2
3.2
0.8
2.1
0.3
1.2
0.2
0.5
0.1
0.3
0.0
$
$
$
$
$
$
$
$
$
$
$
$
$
$
0.25
0.02
5.04
17.62
0.07
0.23
0.52
2.18
2.92
0.15
0.20
0.06
0.04
0.30
57.6
1.4
8.6
22.0
2.4
0.6
1.5
0.2
0.8
0.1
0.3
0.0
0.1
0.0
$
$
$
$
$
$
$
$
$
$
$
$
$
$
8.7
$
0.51
6.9
$
0.41
4.5
$
0.27
$
23.61
22.12
$
$
30.66
27.59
37.9
100.0
$
$
30.01
27.76
38.9
100.0
$
0.32
0.01
5.17
13.30
0.05
0.16
0.37
1.68
1.98
0.07
0.13
0.01
0.01
0.08
31.6
100.0
Figure 3. Basket Price calculation and comparison showing high value MREC product relative to
Brazilian peers. Spot price assumptions https://giti.sg/markets/markets_files. 1 Viridis Mining and
Minerals (ASX:VMM) ASX Announcement “Colossus Maiden Mixed Rare Earth Carbonate (MREC)
Product 24.09.24
Figure 4. Final Mixed rare earth carbonate product, 33.2 grams, produced at the ANSTO facilities in
Sydney.
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
Impurity Removal (MREC)
The presence of impurities in REE-containing solutions has an enormous impact on not only the final REE
products (MREC), but also on the efficiency of processing. Removal of impurities like aluminium and iron
are vital as they can be detrimental to further downstream solvent extraction separation circuits.
Figure 5. Step 2 of impurity removal in the simple 4 step process flow sheet to produce an MREC.
A target pH was determined based on results of the Process Development Program, with freshly
prepared ~20 wt% magnesium oxide slurry added to achieve the impurity removal target pH. A total
residence time of 30 minutes at the target pH was maintained.
The testwork revealed that pH played a significant role in the selective removal of Fe impurities and
resulted in the production of high-purity, industry-grade REEs. Through this method the precipitated
solid primarily contained residual aluminium, silica, and magnesium, with minimal loss of REEs. The
method achieved a high purity level of ~98% with the remaining ~2.0% containing elements listed below
(Figure 5).
BCM (Impurities in MREC)
Impurity
Oxide
Value %
Al2O3
0.52
Alumiumium
Calcium
CaO
0.05
Cobalt
CoO
<0.001
CuO
<0.001
Copper
Iron
Fe2O3
0.06
Potassium
K2O
0.05
Magnesium
MgO
0.52
MnO
0.03
Manganese
Na2O
0.08
Sodium
Nickel
NiO
0.24
Lead
PbO
0.01
Silica
SiO2
<0.2
Zinc
ZnO
0.07
Thorium
Th
<0.001
Uranium
U
0.01
Figure 5. Percentage of impurities carried through to final mixed rare earth carbonate. Impurities
totalled ~2.0%.
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
Composite Bulk Sample
The Bulk Composite sample used to generate the final MREC was formed using ~41kg of ionic clay from
the Ema Project producing 33.2 grams of dry MREC.
This testwork utilised a 41Kg composite sample collected from 12 auger holes over 62 samples drilled at
Ema (Table 1).
Table 1. Hole and sample information which was sent to ANSTO for analysis. See appendix 1 for details.
No. of Holes
No. of Samples
Sample Quantity (kgs)
12
62
41
Figure 6. Ema detailed location map showing location of auger holes used to
make the composite sample sent to ANSTO.
Current Work Program at Ema till December 2024
The Ema project is currently focused on enhancing our understanding of the Mineral Resource Estimate
(see About section below) through an extensive infill drilling program (currently >90% complete) and
ongoing metallurgical assessment. The key work fronts ongoing until the end of December 2024 include;
1. Mineral Resource Infill Drilling
•
•
•
Complete 270-hole infill drilling program, currently >90% complete
Collection of additional density data from deeper horizons to improve the accuracy of the MRE,
now completed
Drill program targeting strategic locations that are likely to yield significant insights into the
mineralization, supporting initial ISR assessment, now completed
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
2. Processing and Metallurgical Testing
•
•
•
Initial ANSTO metallurgical testing and assessment through steps of impurity removal, rare
earths precipitation and MREC final product production to validate process flow sheet, now
complete
Complete magnesium sulfate leaching assays to extract additional data from all infill drilling
holes which will under pin and support both the MRE update and scoping study is complete
Conduct a comprehensive suite of metallurgical tests on a representative master sample to
determine processing characteristics from the current infill program
3. Mineral Resource Estimate update
•
Prepare for the updated Mineral Resource Estimate based on the newly acquired density and
assay data is about to commence
4. Completion of Scoping Study
•
Complete Scoping Study utilising metallurgical testing and mineral resource estimation to
inform the economic viability of the project
This announcement has been authorised for release by the Board of Directors.
For more information:
Andrew Reid
Managing Director
Brazilian Critical Minerals Ltd
E: andrew.reid@braziliancriticalminerals.com
M: +61 432 740 975
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
About Brazilian Critical Minerals Ltd
Brazilian Critical Minerals Limited (BCM) is a mineral
exploration company listed on the Australian Securities
Exchange.
Its major exploration focus is Brazil, in the Apuí region,
where BCM has discovered a world class Ionic Adsorbed
Clay (IAC) Rare Earth Elements deposit. The Ema IAC
project is contained within the 781 km² of exploration
tenements within the Colider Group.
BCM has defined an inferred MRE of 1.02Bt of REE’s with
metallurgical recoveries averaging 68% MREO some of the
highest for these types of deposits anywhere in the world.
The Company is currently converting this MRE from
Inferred into the Indicated category with an extensive drill
program which will inform the scoping study and economic
analysis due for completion in late 2024.
Ema REE Project 2024 Mineral Resource Estimate – by cut-off grade
JORC
Category
cut-off
(ppm)
TREO
Tonnes
(Mt)
TREO
(ppm)
NdPr
(ppm)
DyTb
(ppm)
MREO
(ppm)
MREO:TREO
(%)
Inferred
Inferred
0
500
1,340
1,017
694
793
163
199
15
17
178
216
26
27
Inferred
600
863
836
218
18
236
28
Inferred
700
685
885
237
20
257
29
Inferred
800
494
936
259
21
280
30
Inferred
900
331
977
278
22
300
31
Competent Person Statement
The information in this announcement relates to previously reported exploration results for the
Ema/Ema East Project released by the Company to ASX on 22 May 2023, 17 July 2023, 19 July 2023, 31
July 2023, 13 Sep 2023, 19 Oct 2023, 06 Dec 2023, 06 Feb 2024, 22 Feb 2024, 13 Mar 2024 and 02 Apr
2024. The Company confirms that is not aware of any new information or data that materially affects
the information included in the above-mentioned releases.
The information in this announcement that relates to exploration results is based on information
compiled by Mr. Antonio de Castro, BSc (Hons), MAusIMM, CREA, who acts as BCM´s Senior Consulting
Geologist through the consultancy firm, ADC Geologia Ltda. Mr. de Castro has sufficient experience
which is relevant to the type of deposit under consideration and to the reporting of exploration results
to qualify as a competent person as defined in the 2012 Edition of the Joint Ore Reserves Committee
(JORC) “Australasian Code for Reporting of Exploration Results, Mineral Resources and Ore Reserves”.
Mr. Castro consents to the report being issued in the form and context in which it appears.
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
The information in this announcement that relates to the metallurgical results were compiled by Andrew
Reid who is a permanent employee of Brazilian Critical Minerals Limited and is a Fellow of the Australian
Institute of Mining and Metallurgy (AusIMM). Mr. Reid has sufficient experience that is relevant to the
metallurgical testwork which was undertaken to qualify as a Competent Person as defined in the 2012
JORC Code. Mr. Reid consents to the inclusion in this announcement of the matters based on the
information in the form and context in which it appears.
Appendix 5
The following Table and Sections are provided to ensure compliance with JORC Code (2012 Edition).
JORC (2012) Table 1 – Section 1: Sampling Techniques and Data for auger hole drilling
Item
Sampling
JORC code explanation
Comments
•
•
Exploration results are based on auger drilling conducted by BCM´s
exploration team.
•
The data presented is based on the assay of soils and saprolite by
auger drilling at 1m sample intervals.
•
Sampling was supervised by a GE21 geologist or a GE21 field
assistant.
•
Every 1-metre sample was collected in a big plastic bag in the field
and transported to the exploration shed to be dried in the muffle.
prior to homogenisation.
•
Samples were homogenised and subsequently riffle split with about
1 kg sent to SGS for analysis and a similar amount stored.
•
1 certified blank sample. 1 certified reference material (standard)
samples and 1 field duplicate sample were inserted into the sample
sequence for each 25 samples.
Techniques
•
Drilling
Recovery
Include reference to measures taken to
ensure sample representativity and the
appropriate
calibration
of
any
measurement tools or systems used.
•
Aspects of the determination of
mineralisation that are Material to the
Public Report.
•
In cases where ‘industry standard’ work
has been done this would be relatively
simple (eg ‘reverse circulation drilling was
used to obtain 1 m samples from which 3
kg was pulverised to produce a 30 g charge
for fire assay’). In other cases more
explanation may be required. such as
where there is coarse gold that has
inherent sampling problems. Unusual
commodities or mineralisation types (eg
submarine nodules) may warrant
disclosure of detailed information.
•
Drill type (eg core. reverse circulation.
open-hole hammer. rotary air blast. auger.
Bangka. sonic. etc) and details (eg core
diameter. triple or standard tube. depth of
diamond tails. face-sampling bit or other
type. whether core is oriented and if so. by
what method. etc).
•
Auger drilling was completed by a hand held-mechanical auger with
a 3” auger bit. The drilling is an open hole. meaning there is a
significant chance of contamination from surface and other parts of
the auger hole. Holes are vertical and not oriented.
•
Method of recording and assessing core
and chip sample recoveries and results
assessed.
•
No recoveries are recorded.
•
The operator observes the volume of each metre and notes any
discrepancy.
Techniques
Drill Sample
Nature and quality of sampling (eg cut
channels. random chips. or specific
specialised
industry
standard
measurement tools appropriate to the
minerals under investigation. such as
down hole gamma sondes. or handheld
XRF instruments. etc). These examples
should not be taken as limiting the broad
meaning of sampling.
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
Item
Logging
SubSampling
JORC code explanation
Comments
•
Measures taken to maximise sample
recovery and ensure representative
nature of the samples.
•
No relationship is believed to exist between recovery and grade.
•
Whether a relationship exists between
sample recovery and grade and whether
sample bias may have occurred due to
preferential loss/gain of fine/coarse
material.
•
Whether core and chip samples have been
geologically and geotechnically logged to a
level of detail to support appropriate
Mineral Resource estimation. mining
studies and metallurgical studies.
•
All holes were logged by GE21 geologist. detailing the colour.
weathering. alteration. texture and any geological observations.
Care is taken to identify transported cover from in-situ
saprolite/clay zones and the moisture content. Logging was done to
a level that would support a Mineral Resource Estimate.
•
Whether logging is qualitative or
quantitative in nature. Core (or costean.
channel. etc) photography.
•
Qualitative logging with systematic photography of the stored box.
•
The entire auger hole is logged.
•
The total length and percentage of the
relevant intersections logged.
•
If core. whether cut or sawn and whether
quarter. half or all core taken.
•
Auger sampling procedure is completed in the exploration shed in
Apui.
•
If non-core. whether riffled. tube sampled.
rotary split. etc and whether sampled wet
or dry.
•
•
For all sample types. the nature. quality
and appropriateness of the sample
preparation technique.
The entire one metre sample is bagged on site. in a big plastic bag
which is transported to the exploration shed. where it is dried at
70-90C prior to homogenisation. then quartered to about 1kg to go
to SGS and another 1kg to store on site.
•
Sample preparation for the auger samples was conducted at SGS
Vespasiano (greater Belo Horizonte) comprising oven drying at
100C. crushing of entire sample to 75% < 3mm followed by rotary
splitting and pulverisation of 250 to 300 grams at 95% minus 150#
•
The <3mm rejects and the 250-300 grams pulverised sample were
returned to BCM for storage.
•
Only the last 10 metres of each hole were sent to assay. the
samples above will be send if required.
Techniques
and
Sampling
Procedures
•
•
•
Quality of
Assay Data
and
•
Quality control procedures adopted for all
sub-sampling stages to maximise
representativity of samples.
Measures taken to ensure that the
sampling is representative of the in-situ
material collected. including for instance
results for field duplicate/second-half
sampling.
Whether sample sizes are appropriate to
the grain size of the material being
sampled.
The nature. quality and appropriateness of
the assaying and laboratory procedures
used and whether the technique is
considered partial or total.
ANSTO
•
A Bulk composite of approximately 41kgs was dried at 50°C and
crushed to <1 mm to ensure sample representativity in subsequent
sub-sampling.
•
A small portion (250g) was split out and pulverised to produce
samples for head grade assaying after drying at 105 oC and analysis
using XRF for major gangue elements (Al, Ca, Cu, Fe, K, Mg, Mn, Na,
Ni, P, Si, Sr, Zn).
•
A 600g sample was split to conduct a slurry leach test.
•
The final liquor was assayed were assayed in triplicate by
tetraborate fusion digest/ICP-MS (lithium, tetraborate method) for
rare earth elements (‘REEs’) , U, Th and Sc by ALS Brisbane.
ANSTO completed the assay data and laboratory tests for the Ema
Project, with the aim to produce a Mixed Rare Earth Carbonate
(MREC). The primary objective of the work was to develop a
product utilising magnesium based reagents allowing for a final
demonstration and marketing product to be developed.
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
ASX Announcement
Released 11th November 2024
Item
JORC code explanation
Laboratory
•
Tests
•
For geophysical tools. spectrometers.
handheld XRF instruments. etc. the
parameters used in determining the
analysis including instrument make and
model. reading times. calibrations factors
applied and their derivation. etc.
Nature of quality control procedures
adopted (eg standards. blanks. duplicates.
external laboratory checks) and whether
acceptable levels of accuracy (ie lack of
bias) and precision have been established
Comments
Specific tasks included;
•
Carrying out a large scale slurry leach test on the EMA composite;
•
Carrying out a large scale impurity removal test on liquor
generated from the large scale slurry leach test;
•
Carry out a large scale rare earth carbonate precipitation test on
the IR liquor;
•
Analyse the MREC product for a full suite of elements, including
radionuclides;
Flowsheet for MREC Production:
following key steps:
The process included the
1. Desorption: Leaching was performed using magnesium sulfate
sulphate (0.3M) at pH 4.5, room temperature, and a 30-minute
residence time.
2. Impurity Removal: Using magnesium oxide, a two-stage
precipitation process increased the pH from 4.5 to 7.5 under
ambient conditions.
3. MREC Precipitation: Magnesium bicarbonate was used as a
precipitating agent to produce the final MREC product.
Final Product: MREC with 48.1% recovery of TREY containing 55.3%
TREO and 37.9% of MREO (100% basis) and impurity levels ~<2.0%.
Residual liquids from the desorption and precipitation stages were
analysed to assess impurity removal efficiency. Laboratories and
Analytical Techniques: - ANSTO: Conducted most of the process
tests and analyses using the following techniques: - XRF for major
elements, including Al, Ca, Fe, K, Mg, Mn, Na, Si, and others. - ICPOES for in-house analysis of gangue minerals. ICP-MS for rare earth
elements, including Ce, Dy, Er, Eu, Gd, Ho, La, Lu, Nd, Pr, Sc, Sm, Tb,
Th, Tm, U, Y, and Yb. At the ALS Geochemistry Laboratory:
Performed external analysis of rare earths and radionuclides using
lithium tetraborate fusion digest followed by ICPMS. These tests
confirmed the quality of the MREC product, has low impurity levels,
and complies with market specifications.
Field Samples:
•
1 blank sample. 1 certified reference material (standard) sample
and 1 field duplicate sample were inserted by BBX into each 25sample sequence.
•
Standard laboratory QA/QC procedures were followed. including
inclusion of standard. duplicate and blank samples.
•
The assay results of the standards fall within acceptable tolerance
limits and no material bias is evident.
•
The assay technique used for REE was Lithium Metaborate Fusion
ICP-MS (SGS code ICP95A and IMS95A). This is a recognised industry
standard analysis technique for REE suite and associated elements.
Elements analysed at ppm levels:
Ba
Gd
Rb
U
Cu
Ce
Hf
Sm
V
Ni
Cr
Ho
Sn
W
Cs
La
Sr
Y
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
Dy
Lu
Ta
Yb
Er
Nb
Tb
Zr
Eu
Nd
Th
Zn
Ga
Pr
Tm
Co
ASX Announcement
Released 11th November 2024
Item
JORC code explanation
Comments
The sample preparation and assay techniques used are industry
standard and provide total analysis.
The ICP95A reports the major elements oxides used to calculate
the Chemical Index of Alteration (CIA) at % levels included:
Al2O3
CaO
Cr2O3
F2O3
K2O
MgO
MnO
Na2O
P2O5
SiO2
TiO2
Verification
The SGS laboratory used for the RRE assays is ISO 9001 and 14001
and 17025 accredited.
•
Analytical standard for REE ITAK-713 and 714 were used as CRM
material in the batches sent to SGS.
•
The assay results for the standards were consistent with the
certified levels of accuracy and precision and no bias is evident.
•
The blanks used contain some REE. with critical elements Ce. Nd.
Dy and Y present in small quantities.
•
Duplicate samples were allocated separate sample numbers and
submitted with the same analytical batch as the primary sample.
Variability between duplicate results is considered acceptable and
no sampling bias is evident.
•
Laboratory inserted standards. blanks and duplicates were
analysed as per industry standard practice. There is no evidence of
bias from these results.
•
The verification of significant intersections
by either independent or alternative
company personnel.
•
Apart from the routine QA/QC procedures by the Company and the
laboratory. there was no other independent or alternative
verification of sampling and assaying procedures.
•
The use of twinned holes.
•
•
Documentation of primary data. data
entry procedures. data verification. data
storage
(physical
and
electronic)
protocols.
Analytical results for REE were supplied digitally. directly from the
SGS laboratory in Vespasiano to the BCMs Exploration Manager in
Rio de Janeiro.
•
No twinned holes were used.
•
Geological data was logged onto paper and transferred to Excel
spreadsheets at end of the day and then transferred into the drill
hole database. Microsoft Access is used for database storage and
management and incorporates numerous data validation and data
integrity checks. All assay data is imported directly into the
Microsoft Access database.
•
No adjustments were made to the data.
•
All REE assay data received from the laboratory in element form is
unadjusted for data entry.
•
Conversion of elements analysis (REE) to stoichiometric oxide (REO)
was undertaken by spreadsheet using defined conversion factors.
(Source:https://www.jcu.edu.au/advanced-analyticalcentre/resources/element-to-stoichiometric-oxide-conversionfactors).
of Sampling
and Assaying
•
•
Discuss any adjustment to assay data.
Element ppm
Ce
Dy
Er
Eu
Conversion Factor
1.2284
1.1477
1.1435
1.1579
Brazilian Critical Minerals Ltd (ABN: 82 089 221 634)
AUS: Brookfield Place, Level 11, 125 St Georges Terrace, Perth WA 6000 T +61 8 6383 7820
BRA: Av Jornalista Riccardo Marinho, 360, Sala 113, Barra da Tijuca, Rio de Janeiro T +55 21 2439 57
Oxide Form
CeO2
Dy2O3
Er2O3
Eu2O3
ASX Announcement
Released 11th November 2024
Item
JORC code explanation
Comments
Gd
1.1526
Gd2O3
Ho
1.1455
Ho2O3
La
1.1728
La2O3
Lu
1.
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